Palladium-Catalyzed Direct Dicarbonylation of Amines with Ethylene to Imides
The selective and effective conversion of low-cost and simple bulk chemicals into high value-added products through catalytic strategy has a wide range of practical significance. Here, a palladium-catalyzed method for the direct and efficient dicarbonylation of amines with basic industrial feedstock ethylene to imide has been developed. Moderate to excellent yields of the desired imides can be produced from readily available amines in a straightforward manner.
AlMe3-promoted formation of amides from acids and amines
In the presence of AlMe3, amines can be directly coupled with acids through dimethylaluminum amide intermediates to form the corresponding amides. A wide range of amines and acids including less nucleophilic amines, bulky amines, unprotected se
Li, Jianqing,Subramaniam, Krishnananthan,Smith, Daniel,Qiao, Jennifer X.,Li, Jie Jack,Qian-Cutrone, Jingfang,Kadow, John F.,Vite, Gregory D.,Chen, Bang-Chi
supporting information; experimental part
p. 214 - 217
(2012/02/16)
NEW METHOD OF PREPARING 2-ACYLAMINOTHIAZOLES
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Kravchenya, N. A.
p. 593 - 594
(2007/10/02)
SYNTHESIS OF NITAZOLE AND ITS ANALOGS
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Kravchenya, N. A.
p. 809 - 810
(2007/10/02)
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