cas 35138-22-8, Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | Articles data ｜lookchem

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35138-22-8

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'Diopium', a chiral phosphoniophosphine derived from Kagan's diop. Rhodium complexes and reducing catalytic properties
Cationic chiral monophosphines are devised as a novel type of ligands for catalytic transformations of polar substrates with polar reagents. A phosphonio-phosphine derived from (R,R)-diop ('methyldiopium') proved to act as a chiral version of Baird's ω-phosphonio-phosphine ligands ('phophos') in Rh(I) complexes in both 1:1 and 2:1 P:Rh stoichiometry. Their versatile structure in CDCl3 solution has been studied by NMR spectroscopy in the presence of various anions (Cl-, I-, BF4-, PF6-). The in situ 2.5:1 methyldiopium-Rh catalytic system slowly hydrogenated (Z)-α-acetamidocinnamic acid in 63% conversion and 5% ee. This system was, however, specifically active in a novel hydrogen transfer procedure by a 1:1 HCOOH:NEt3 mixture under mild conditions (40 C, in the absence of DMSO), for which the corresponding diop-Rh system was not active. Itaconic acid was thus quantitatively reduced to racemic methylsuccinic acid. (Z)-α-acetamidocinnamic acid was reduced in up to 85% conversion to N-acetylphenylalanine in various solvents. Though still moderate, the ee's depend on the solvent: 10% in (R) product in THF, 14% in (S) product in acetonitrile.
Viau, Lydie,Chauvin, Remi
p. 180 - 186
(2002)
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Chemical Properties

Appearance/Colour :dark red
Melting Point: 210 °C
Density: 0.42 g/cm3 (20℃)
Storage Temp.:Refrigerator (+4°C)
Sensitive: Slightly air & moisture sens
PSA: 0.00000
LogP: 6.64560

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