Photorearrangement of 5,6-Dichloro-1,4-dihydro-1,4-dimethylpyrazine-2,3-dione and its Further Reactions
On u.v. irradiation the title dione (4) rearranges to 2-(dichloromethylene)-1,3-dimethylimidazolidine-4,5-dione (7) (with thermal reversibility); however, in the presence of moisture dimethylimidazolidinetrione (5) is formed, via (6).
Wamhoff, Heinrich,Kleimann, Wolfgang
p. 743 - 744
(2007/10/02)
The synthesis and reactions of a tetrachlorodioxopiperazine.
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Ottenheym,Spande,Witkop
p. 3358 - 3360
(2007/10/06)
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