Cooperative effect of two metals: CoPd(OAc)4-catalyzed C-H amination and aziridination
The first Co/Pd-cocatalyzed intramolecular C-H amination and aziridination reactions were developed. Sulfamate esters were converted to oxathiazinanes by using CoPd(OAc)4 as catalyst and PhI(OAc)2 as oxidant. The mutual presence of b
Huang, Guan-Hao,Li, Jian-Min,Huang, Jing-Jyun,Lin, Jyun-Dai,Chuang, Gary Jing
A mechanistic analysis of the Rh-catalyzed intramolecular C-H amination reaction
A detailed mechanistic investigation of the intramolecular dirhodium tetracarboxylate-catalyzed sulfamate ester C-H amination reaction is presented. These studies provide support for the formation of a sulfamate-derived iminoiodinane, which reacts rapidly
Fiori, Kristin Williams,Espino, Christine G.,Brodsky, Benjamin H.,Du Bois
experimental part
p. 3042 - 3051
(2009/09/27)
Synthesis of 1,3-difunctionalized amine derivatives through selective C-H bond oxidation
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Espino,Wehn,Chow,Du Bois
p. 6935 - 6936
(2007/10/03)
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