Versatile and mild synthesis of Di- and trisaccharidic 2-enopyranosyl cyanides by cyanation of per-O-acetylglycals with trimethylsilyl cyanide catalyzed by palladium(II) acetate
A catalytic amount (1-2 mol%) of palladium(II) acetate was found to work as a catalyst for the cyanation of di- and trisaccharidic per-O-acetylglycals with trimethylsilyl cyanide to afford di- and trisaccharidic 2-enopyranosyl cyanides in high yields and in moderate stereoselectivities. Georg Thieme Verlag Stuttgart.
Xu, Xiaoyong,Tan, Qitao,Hayashi, Masahiko
p. 770 - 776
(2008/09/21)
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