Regioselective aminobromination of terminal alkenes
The addition of t-butyl N,N-dibromocarbamate (BBC) to a variety of terminal alkenes has been studied. The reaction was spontaneously initiated and proceeded smoothly in refluxing dichloromethane. The N-bromo adducts, formed upon addition, could be reduced
?liwińska, Anna,Zwierzak, Andrzej
p. 5927 - 5934
(2007/10/03)
t-Butyl N,N-dibromocarbamate (BBC) - New reagent for aminobromination of terminal alkenes
t-Butyl N,N-dibromocarbamate, easily obtained by bromination of t-butyl carbamate in aqueous potassium carbonate, reacts smoothly with a variety of terminal alkenes to afford the corresponding β-bromo-N-Boc-amines upon reduction with aqueous sodium sulphi
Klepacz, Anna,Zwierzak, Andrzej
p. 4539 - 4540
(2007/10/03)
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