Tandem hydroboration/reduction of trisubstituted β,γ-unsaturated esters for the asymmetric synthesis of chiral 1,3-diols
Treatment of a range of trisubstituted β,γ-unsaturated esters with 2 equiv of (-)-monoisopinocampheylborane results in hydroboration of their alkene functionalities and reduction of their ester groups to afford chiral 1,3-diols containing two new vicinal
Fordred, Paul S.,Bull, Steven D.
p. 27 - 31
(2013/02/21)
Acyclic Stereoselection. 16. High Diastereofacial Selectivity in Lewis Acid Mediated Additions of Enolsilanes to Chiral Aldehydes
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Heathcock, Clayton H.,Flippin, Lee A.
p. 1667 - 1668
(2007/10/02)
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