36528-62-8

Basic information

• Product Name: 5,6-dimethylidenebicyclo[2.2.2]oct-2-ene
• Synonyms: Bicyclo(2.2.2)oct-2-ene, 5,6-bis(methylene)-
• CAS NO: 36528-62-8
• Molecular Formula: C₁₀H₁₂
• Molecular Weight: 132.2023
• Mol File: 36528-62-8.mol

Chemical Properties

• Boiling Point: 184.6°C at 760 mmHg
• Flash Point: 45.8°C
• Density: 0.93g/cm³
• Vapor Pressure: 0.997mmHg at 25°C
• Refractive Index: 1.524
• CAS DataBase Reference: 5,6-dimethylidenebicyclo[2.2.2]oct-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 5,6-dimethylidenebicyclo[2.2.2]oct-2-ene(36528-62-8)
• EPA Substance Registry System: 5,6-dimethylidenebicyclo[2.2.2]oct-2-ene(36528-62-8)

Safety Data

• Hazardous Substances Data: 36528-62-8(Hazardous Substances Data)

Upstream product

• 17441-67-7 (3-Hydroxymethyl-bicyclo[2.2.2]oct-5-en-2-yl)-methanol 
• 54290-45-8 p-toluenesulfonate of endo-2,3-bis(hydroxymethyl)bicyclo<2.2.2>oct-5-ene 
• 361451-37-8 5,6-bis(iodomethyl)bicyclo[2.2.2]-oct-2-ene 
• 74-83-9 methyl bromide 
• 6715-27-1 C₁₄H₂₆N₂ 

Relevant articles and documents

Prepackaged Ramberg-B?cklund reagents: Useful tools for organic synthesis

The synthesis and reactions of several α,β-unsaturated chloromethyl sulfones is presented, for example [(chloromethyl)sulfonyl]-1,3- propadiene (4), [(chloromethyl)sulfonyl]ethene (5), [(dichloromethyl)sulfonyl] ethene (6) and (E,Z)-1,2-bis[(chloromethyl)

First synthesis of stable 5-alkyl- or 4,5-dialkyl-substituted 1,2-thiazinylium salt

5-t-Butyl-1,2-thiazinylium 6c and rigid 5,8-ethano-5,8-dihydrobenzo[d]-1,2-thiazinylium salts 17 without conjugated stabilization with the aromatic ring at the 4- or 5-position of the thiazine ring have been successfully obtained as crystals.