367953-72-8Relevant articles and documents
Asymmetric ring-opening reaction of meso -epoxides with aromatic amines using homochiral metal-organic frameworks as recyclable heterogeneous catalysts
Tanaka, Koichi,Kinoshita, Maya,Kayahara, Jun,Uebayashi, Yutaro,Nakaji, Kazusada,Morawiak, Maja,Urbanczyk-Lipkowska, Zofia
, p. 28139 - 28146 (2018/08/16)
An efficient asymmetric ring-opening (ARO) reaction of meso-epoxides with aromatic amines catalysed by a series of homochiral metal-organic frameworks (MOFs) was carried out. Excellent results (up to 95% ee) for the ARO of cyclohexene oxide with several a
Zn(ii)-catalyzed desymmetrization of meso-epoxides by aromatic amines in water
Bonollo, Simona,Frineuelli, Francesco,Pizzo, Ferdinando,Vaccaro, Luigi
experimental part, p. 1574 - 1578 (2009/04/07)
The Zn(OTf)2-SDS-bipyridine 1 system has proved to be an effective catalyst in water for the desymmetrization of ep-oxides 2a-d by anilines 3a-d. After obtaining comparable results by using Sc(III)-SDS and Zn(II)-SDS systems in the case of 2a and 3a, we h