368423-20-5Relevant articles and documents
Enantiomerically pure α-pinene derivatives from material of 65% enantiomeric purity. Part 2: C2-symmetric N,N′-3-(2α- hydroxy)pinane diimines and diamines
Markowicz, Stanislaw W.,Figlus, Marek,Lejkowski, Michal,Karolak-Wojciechowska, Janina,Dzierzawska-Majewska, Agnieszka,Verpoort, Francis
, p. 434 - 448 (2006)
The conversion of enantiomerically enriched (ee >99%) 2α-hydroxypinan-3-one and its oxime (obtained in previously described procedures* from α-pinene of 65% ee) into a range of derivatives with potential application in asymmetric synthesis was attempted.
Transformations of peroxide products of olefin ozonolysis in tetrahydrofuran in reactions with hydroxylamine and semicarbazide hydrochlorides
Ishmuratov,Legostaeva,Garifullina,Botsman,Muslukhov,Ishmuratova,Tolstikov
, p. 928 - 933 (2014/10/15)
Treatment with hydroxylamine and semicarbazide hydrochlorides of peroxide products obtained by ozonolysis of olefins in tetrahydrofuran gives mainly carboxylic acids and their derivatives.
Transformation of peroxide products of olefin ozonolysis under treatment with hydroxylamine and semicarbazide hydrochlorides in acetic acid
Ishmuratov,Legostaeva,Garifullina,Botsman,Muslukhov,Tolstikov
, p. 1075 - 1081 (2015/02/02)
Hydrochlorides of hydroxylamine and semicarbazide efficiently reduce peroxide products of olefin ozonolysis in a system CH2Cl2-AcOH leading to the formation of carboxylic acids and their derivatives. The application of water as the solvent component favors the increase in the fraction of nitrogen-containing organic compounds (semicarbazones, keto- and aldoximes, nitriles) and reduction in the yield of carboxylic acids.
Synthesis of highly functionalized chiral nitriles by radical fragmentation of β-hydroxy azides. Convenient transformation of aldononitriles into 1,4- and 1,5-iminoalditols
Hernandez, Rosendo,Leon, Elisa I.,Moreno, Pilar,Riesco-Fagundo, Concepcion,Suarez, Ernesto
, p. 8437 - 8444 (2007/10/03)
The synthesis of highly functionalized nitriles by an alkoxyl radical fragmentation of cyclic β-hydroxy azides is described. The alkoxyl radicals were generated by reaction of the alcohols with (diacetoxyiodo)benzene and iodine under mild conditions compa
A novel CAN-mediated oxidative rearrangement of monoterpenes
Nair, Vijay,Rajan, Roshini,Balagopal, Lakshmi,Thomas, Siji,Narasimlu
, p. 8971 - 8974 (2007/10/03)
A facile CAN-mediated oxidative rearrangement of monoterpenes of the pinene family to afford bisamides and ether derivatives is described.
Conversion of Terpenic Compounds to ω-Ketonitriles
Tkachev, A.V.,Rukavishnikov, A.V.,Chibirjaev, A.M.,Volodarsky, L.B.
, p. 2123 - 2132 (2007/10/02)
Conversion of unsaturated terpenoids with trisubstituted carbon-carbon double bond into α-aminooximes followed by treatment with phosphorus pentachloride results in the formation of seco-terpenic ω-ketonitriles.
