374633-33-7

Basic information

• Product Name: 3-BROMO-2-HYDROXY-6-PICOLINE
• Synonyms: 5-Bromo-6-hydroxy-2-picoline;3-BROMO-2-HYDROXY-6-PICOLINE;3-BROMO-6-METHYL-PYRIDIN-2-OL;2-hydroxy-3-bromo-6-methylpyridine;2-HYDROXY-3-BROMO-6-PICOLINE;3-BROMO-2-HYDROXY-6-METHYLPYRIDINE;2-HYDROXY-3-BROMO-6-METHYLPYRIDINE 98%;2(1H)-Pyridinone, 3-bromo-6-methyl-
• CAS NO: 374633-33-7
• Molecular Formula: C₆H₆BrNO
• Molecular Weight: 188.02
• Product Categories: Pyridine;Pyridines
• Mol File: 374633-33-7.mol

Chemical Properties

• Boiling Point: 326.8 °C at 760 mmHg
• Flash Point: 151.4 °C
• Appearance: /
• Density: 1.5296 (rough estimate)
• Vapor Pressure: 0.000211mmHg at 25°C
• Refractive Index: 1.5500 (estimate)
• Storage Temp.: Inert atmosphere,Room Temperature
• PKA: 10.63±0.10(Predicted)
• CAS DataBase Reference: 3-BROMO-2-HYDROXY-6-PICOLINE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMO-2-HYDROXY-6-PICOLINE(374633-33-7)
• EPA Substance Registry System: 3-BROMO-2-HYDROXY-6-PICOLINE(374633-33-7)

Safety Data

• Hazardous Substances Data: 374633-33-7(Hazardous Substances Data)

Usage

Physical Form

White to Yellow Solid

InChI:InChI=1/C6H6BrNO/c1-4-2-3-5(7)6(9)8-4/h2-3H,1H3,(H,8,9)

Upstream product

• 500587-45-1 3,5-dibromo-2-hydroxy-6-methylpyridine 
• 3279-76-3 6-hydroxy-2-methylpyridine 

Downstream Products

• 874493-25-1 3-bromo-6-methyl-5-nitro-pyridin-2-ol 
• 1049707-80-3 2-(4-chloro-3-trifluoromethylphenoxy)-6-methyl-5-nitro-3-trimethylsilanylethynylpyridine 
• 1049707-76-7 2-(4-chloro-3-trifluoromethylphenoxy)-3-(4-fluorophenyl)-6-methyl-5-nitropyridine 
• 1049707-78-9 6-(4-chloro-3-trifluoromethylphenoxy)-5-(4-fluorophenyl)-2-methylpyridin-3-ylamine 
• 1049707-82-5 6-(4-chloro-3-trifluoromethylphenoxy)-5-ethynyl-2-methylpyridin-3-ylamine 
• 1049707-75-6 3-bromo-2-(4-chloro-3-trifluoromethylphenoxy)-6-methyl-5-nitropyridine 
• 1049707-79-0 5-bromo-6-(4-chloro-3-trifluoromethylphenoxy)-2-methylpyridin-3-ylamine 
• 1049706-79-7 3-[5-bromo-2-methyl-6-(4-methylpentyloxy)pyridin-3-yl]-1-isopropyl-1-methylthiourea 

Relevant articles and documents

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Efficient regioselective preparation of monobromo and bromoiodo hydroxy pyridines from dibromoderivatives via bromine-lithium exchange

Annular dibromination of hydroxypyridines with NBS in acetonitrile followed by bromine-lithium exchange with RLi and subsequent trapping with H2O or I2 afforded monobromo and bromoiodo derivatives in a completely regioselective way. Iodination of bromo hydroxypyridines with NIS is totally regioselective.