Nucleophilic addition to acetylenes in superbasic catalytic systems: XVIII. Vinylation of phenols and naphthols with acetylene
Phenols and naphthols react with acetylene in a superbasic system KOH-DMSO forming the corresponding aryl vinyl ethers in up to 80% yields.
Trofimov,Oparina,Kolyvanov,Vysotskaya,Gusarova
p. 188 - 194
(2015/04/14)
Iridium-catalyzed synthesis of vinyl ethers from alcohols and vinyl acetate
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Hirabayashi, Tomotaka,Sakaguchi, Satoshi,Ishii, Yasutaka,Davies, Paul W.,Fürstner, Alois
p. 55 - 58
(2017/09/25)
Development of a highly efficient catalytic method for synthesis of vinyl ethers
A new method for the preparation of alkyl vinyl ethers has been developed. Thus, various types of alkyl vinyl ethers were synthesized by the reaction of alcohols with vinyl acetate under the influence of a catalytic amount of [Ir(cod)Cl]2 combined with Na2CO3 in good to excellent yields. Copyright