Pyrazole Chemistry I: Efficient Syntheses of Aryl or Benzyl 4-Pyrazolyl Ketones and Carbinols
Dilithiation of 4-bromopyrazole followed by reaction with appropriate electrophiles provides an improved access to 4-benzoylpyrazole (3) and the corresponding alcohol 4a.In a similar manner the homologous compounds 5 and 7 are conveniently available.
Synthetic inhibitors of alcohol dehydrogenase. Pyrazoles containing an unsaturated hydrocarbon residue in the 4-position.
A series of pyrazoles containing an unsaturated hydrocarbon residue in the 4-position has been synthesized and tested for ability to inhibit the activity of the enzyme liver alcohol dehydrogenase. These compounds were found to be less active than the corr
Tolf,Dahlbom,Theorell,Akeson
p. 101 - 107
(2007/10/02)
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