Synthesis of esters of D, L-, D(+)-, and L(-)-camphor oximes: Structure-odor correlation
Esters of D,L-, D(+)-, and L(-)-camphor oximes were synthesized, and the correlation between their structure and odor was examined.
Dikusar,Zhukovskaya,Vyglazov
p. 1982 - 1985
(2008/02/08)
Stereochemical Assignment of Camphoroxime by PMR Spectroscopy Using Tris(dipivalomethanato)europium(III)
Stereochemistry of camphoroxime has been deciphered with the help of PMR spectroscopy using tris(dipivalomethanato)europium (III) as a shift reagent.The hydroxyl group in the oxime has been shown to be syn to γ-methyl on the basis of its anisotropic effect as well as the pronounced paramagnetic induced shift of the γ-methyl.Three methyl (α-, β- and γ-) resonances have also been rationalised using various concentrations of the shift reagent.
Singh, Ashok Kumar,Verma, Shiva Mohan
p. 33 - 35
(2007/10/02)
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