Strategies for the total asymmetric synthesis of heliannuols K and L: Scope and limitations
Kulinkovich reactions of oxa-esters bearing terminal double bonds afford cyclopropanols by intramolecular cyclization. These can undergo Saegusa oxidation to provide β-chlorooxacycloalkanones and can then be then dehydrohalogenated into oxacycloalkenones.
Lecornue, Frederic,Paugam, Renee,Ollivier, Jean
p. 2589 - 2598
(2007/10/03)
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