- A new class of organogelators based on triphenylmethyl derivatives of primary alcohols: Hydrophobic interactions alone can mediate gelation
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In the present work, we have explored the use of the triphenylmethyl group, a commonly used protecting group for primary alcohols as a gelling structural component in the design of molecular gelators. We synthesized a small library of triphenylmethyl deri
- Singh, Wangkhem P.,Singh, Rajkumar S.
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supporting information
p. 138 - 149
(2017/02/15)
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- Influence of the spacer length on the phase behaviors of mesogen-jacketed liquid crystalline polymers with a bulk side-chain
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A series of mesogen-jacketed liquid-crystalline polymers (MJLCPs) containing two triphenylmethyl (Tr) units in the side chains, named poly{2,5-bis[(triphenylmethoxy-alkyl)oxycarbonyl]-styrenes} (denoted as Pv-m-Tr, m = 2, 4, 6, 8, 10, 12, which is the num
- Luo, Yongbing,Chen, Sheng,Zhang, Hailiang
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p. 54920 - 54928
(2015/07/07)
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- Elaboration of the ether cleaving ability and selectivity of the classical Pearlman's catalyst [Pd(OH)2/C]: Concise synthesis of a precursor for a myo-inositol pyrophosphate
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The cleavage of propargyl, allyl, benzyl, and PMB ethers by Pd(OH) 2/C can be tuned in that order, by varying the reaction conditions. Other moieties such as C-C double bonds, esters, trityl ether, p-bromo and p-nitrobenzyl ethers are stable to these reaction conditions. Cleavage of allyl ethers can be made catalytic by using 1:1 mixture of Pd(OH)2/C and Pd/C. The synthetic potential of the selective ether cleaving ability of Pd(OH)2/C, essentially under neutral conditions, has been demonstrated by an efficient synthesis of a precursor for the preparation of an inositol pyrophosphate derivative.
- Mart, Alson,Shashidhar, Mysore S.
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p. 9769 - 9776,8
(2012/12/11)
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- Elaboration of the ether cleaving ability and selectivity of the classical Pearlman's catalyst [Pd(OH)2/C]: Concise synthesis of a precursor for a myo-inositol pyrophosphate
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The cleavage of propargyl, allyl, benzyl, and PMB ethers by Pd(OH) 2/C can be tuned in that order, by varying the reaction conditions. Other moieties such as C-C double bonds, esters, trityl ether, p-bromo and p-nitrobenzyl ethers are stable to these reaction conditions. Cleavage of allyl ethers can be made catalytic by using 1:1 mixture of Pd(OH)2/C and Pd/C. The synthetic potential of the selective ether cleaving ability of Pd(OH)2/C, essentially under neutral conditions, has been demonstrated by an efficient synthesis of a precursor for the preparation of an inositol pyrophosphate derivative.
- Mart, Alson,Shashidhar, Mysore S.
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p. 9769 - 9776
(2013/01/13)
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- N1-substituted thymine derivatives as mitochondrial thymidine kinase (TK-2) inhibitors
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Novel N1-substituted thymine derivatives related to 1-[(Z)-4-(triphenylmethoxy)-2-butenyl]thymine have been synthesized and evaluated against thymidine kinase-2 (TK-2) and related nucleoside kinases [i.e., Drosophila melanogaster deoxynucleosid
- Hernández, Ana-Isabel,Familiar, Olga,Negri, Ana,Rodríguez-Barrios, Fátima,Gago, Federico,Karlsson, Anna,Camarasa, María-José,Balzarini, Jan,Pérez-Pérez, María-Jesús
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p. 7766 - 7773
(2007/10/03)
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- Macrocyclic diacylglycerol-bis-lactones as conformationally constrained analogues of diacylglycerol-lactones. Interactions with protein kinase C
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A series of macrocyclic diacylglycerol (DAG)-bis-lactones were investigated as extreme conformationally constrained analogues of DAG-lactones in order to seek more potent protein kinase C (PKC) ligands with higher binding affinities and less lipophilicity
- Kang, Ji-Hye,Kim, Su Yeon,Lee, Jeewoo,Marquez, Victor E.,Lewin, Nancy E.,Pearce, Larry V.,Blumberg, Peter M.
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p. 4000 - 4007
(2007/10/03)
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- Selective deprotection of t-butyldiphenylsilyl ethers in the presence of t-butyldimethylsilyl ethers by tetrabutylammonium fluoride, acetic acid, and water
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The selective deprotection of t-butyldiphenylsilyl ethers in the presence of t-butyldimethylsilyl ethers by tetrabutylammonium fluoride, acetic acid, and water has been realize.
- Higashibayashi,Shinko,Ishizu,Hashimoto,Shirahama,Nakata
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p. 1306 - 1308
(2007/10/03)
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- Synthesis of Tethered Trisaccharides to Probe Inter-Saccharide Flexibility in Carbohydrate - Protein Interactions
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Two crystal structures of the trisaccharide epitope α-D-Galp(1→2)[α-D-Abep(1→3)α-D-Manp1→OCH 3 1 bound to antibody Fab and single-chain Fv fragments have been used to guide the design of an intramolecular tether that constrains the trisaccharid
- Alibes, Ramon,Bundle, David R.
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p. 6288 - 6301
(2007/10/03)
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