- Accessing the structural diversity of pyridone alkaloids: Concise total synthesis of rac-citridone A
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A unique route to the structural diversity of pyridone alkaloids is described based on the concept of a common synthetic strategy. Three different core structure analogues corresponding to akanthomycin, septoriamycin A, and citridone A have been prepared by using a highly selective and novel carbocyclization reaction.
- Fotiadou, Anna D.,Zografos, Alexandros L.
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supporting information; experimental part
p. 4592 - 4595
(2011/10/17)
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- Synthesis of (2R,4R)-supellapyrone, the sex pheromone of the brownbanded cockroach, Supella longipalpa, and its three stereoisomers
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Supellapyrone [(2R,4R)-5-(2,4-dimethyl)-3-methyl-2H-pyran-2-one (1)], the female sex pheromone of the brownbanded cockroach (Supella longipalpa), and its three stereoisomers were synthesized by employing lipase-catalyzed desymmetrization or enantiomer separation of syn- or anti-2,4-dimethylpentane-1,5-diol (9) as the key step.
- Fujita, Ken,Mori, Kenji
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p. 493 - 502
(2007/10/03)
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