The selective functionalization of saturated hydrocarbons. Part 40. Aspects of Fe(II) based peroxide fragmentation in pyridine solution
The Haber-Weiss mechanism does not apply to the Fe(II) induced fragmentation of primary and secondary hydroperoxides in pyridine. However, it does apply to tertiary hydroperoxides. Steric bulk is an important factor in Fe(II) induced dialkyl peroxide decomposition in pyridine. On the contrary in tetrahydrofuran a different relatively unhindered electron transfer process predominates where the Fe(II) becomes a catalyst.
Barton, Derek H. R.,Launay, Franck
p. 14565 - 14578
(2007/10/03)
An Easy Access to Unsymmetrical Peroxides
Unsymmetrical peroxides could be prepared easily by reaction of alkyl hydroperoxides with primary and secondary alkyl bromides and methanesulfonates in tetrahydrofuran in the presence of potassium hydroxide and polyethyleneglycol 400.
Bourgeois, Marie-Josephe,Montaudon, Evelyne,Maillard, Bernard
p. 700 - 701
(2007/10/02)
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