- PRODUCTION AND PROPERTIES OF N-BENZYLIDENEPERCHLOROVINYLAMINE
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The action of triethylamine on the readily obtainable N-benzyltrichloroacetimidoyl chloride gives a high yield of N-benzylideneperchlorovinylamine (CCl2=CClN=CHC6H5), which adds chlorine under mild conditions and gives a mixture of two chlorotropic tautomers, i. e., N-benzylideneperchloroethylamine and N-1-chlorobenzyltrichloroacetimidoyl chloride.It was possible to demonstrate the chlorotropic equilibrium in the -CCl2-N=CH- -CCl=N-CHCl- system by means of the PMR spectra.
- Drach, B. S.,Popovich, T. P.,Kalinin, V. N.,Kovalev, V. A.,Soifer, G. B.,et al.
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p. 1762 - 1765
(2007/10/02)
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- Gem-bis amide herbicide antidote compositions and methods of use
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Herbicidal compositions comprising an active herbicidal compound and antidote therefor and methods of use; the antidote compound corresponds to substituted gem-bis amides having the formula EQU1 in which R is selected from the group alkyl, alkenyl, phenyl, phenalkyl, naphthyl, cyanoalkyl, and substituted phenyl wherein said substituents are selected from the group methoxy, nitro, chloro, bromo-3,4-methylenedioxy, mono- and di-substituted lower alkyl; and R1 is lower haloalkyl.
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