Electrochemical Reduction of Alkyl Aryl and Dialkyl Trithiocarbonates
Electrochemical reduction in aprotic medium of alkyl aryl trithiocarbonates (1a-c) in the presence of an alkylating agent gives tetraalkyltetrathioethylenes (2a-c); under similar conditions dialkyl trithiocarbonates (3a-c) also form 2, but the reaction is complicated by the ability of 3 to act as an alkylating agent.The mechanisms of the reactions are discussed on the basis of the preparative and cyclic voltammetric results.
Falsig, Mogens,Lund, Henning
p. 545 - 550
(2007/10/02)
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