Carbanionic route to electroactive carbon-centered anion and radical oligomers
Figure Presented. The synthesis of poly-1,3-bisdiphenylene-2-phenyl allyl (BDPA) radicals via a new anionic oligomerization strategy is reported. The material displays a reversible reduction from the orange-red radical to the blue carbanion in solution.
Dane, Eric L.,Swager, Timothy M.
supporting information; experimental part
p. 4324 - 4327
(2010/11/18)
NOVEL ELECTRON TRANSFER MECHANISM IN LITHIUM ALANATE REDUCTION OF BENZYLIC HALIDES
Occurence of a new electron transfer mechanism in the LiAlH4 reduction of 9-chloromethylanthracene, diphenylchloromethane and 9-bromofluorene is demonstrated.Alanate anion serves as a source of electrons and hydrogen atoms.
Singh, P. R.,Khurana, J. M.,Nigam, Alok
p. 2901 - 2904
(2007/10/02)
More Articles about upstream products of 39168-58-6