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401-85-4

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Deoxofluorination of (Hetero)aromatic Acids
Diverse trifluoromethyl-substituted compounds were synthesized by deoxofluorination of cinnamic and (hetero)aromatic carboxylic acids with sulfur tetrafluoride. The obtained products were used as starting materials in the preparation of novel fluorinated amino acids, anilines, and aliphatic amines - valuable building blocks for medicinal chemistry and agrochemistry.
Alekseenko, Anatoliy N.,Bugera, Maksym Ya.,Gerus, Igor I.,Kiriakov, Oleksandr,Klipkov, Anton A.,Mykhailiuk, Pavel K.,Pustovit, Yurii,Razhyk, Bohdan,Semenov, Sergey,Starova, Viktoriia S.,Tananaiko, Oksana Yu.,Tarasenko, Karen,Tolmachev, Andrei A.,Trofymchuk, Serhii,Zaporozhets, Olga A.
p. 3110 - 3124
(2020/03/23)

Fluoroform-derived CuCF3 for low-cost, simple, efficient, and safe trifluoromethylation of aryl boronic acids in air
Easy does it: Aryl boronic acids undergo smooth and selective trifluoromethylation with low-cost fluoroform-derived CuCF3 in DMF in non-dried air. The reaction occurs under mild conditions (1 atm, room temperature), exhibits unprecedented funct
Novak, Petr,Lishchynskyi, Anton,Grushin, Vladimir V.
supporting information; experimental part
p. 7767 - 7770
(2012/08/29)

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134099-34-6
2,6-difluoro-4-(trifluoromethyl)benzaldehyde

Chemical Properties

Melting Point: -40 °C
Boiling Point: 95.6 °C at 760 mmHg
Flash Point:20.5 °C
Density: 1.386 g/cm³
Vapor Pressure: 51.6mmHg at 25°C
Refractive Index: 1.391
PSA: 0.00000
LogP: 2.98360

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