- Syntheses, structures, and reactivity studies of half-open ruthenocenes and their oxodienyl analogues
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Improved synthetic routes to Cp*Ru(Pdl) complexes (Pdl = 2,4-dimethylpentadienyl and various oxodienyl ligands) including Cp*Ru(η5-2,4-Me2-C4 H3O) (1), Cp*Ru[η5-2,4-(t-Bu)2-C4 H3O] (1'), and Cp*ru(η5-2,4-Me2-C5 H5) (1″) were developed. When chelating, diphosphines were used as coligands and reactions with O2, Cl2 or H2 led to oxidative addition. A carbon-carbon bond activation was reported.
- Navarro Clemente, M. Elena,Saavedra, Patricia Juárez,Vásquez, Marisol Cervantes,Angeles Paz-Sandoval,Arif, Atta M.,Ernst, Richard D.
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p. 592 - 605
(2008/10/08)
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