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Lanthanum(III) chloride bis(lithium chloride) complex solution 0.6 M in THF is a chemical compound that consists of lanthanum(III) chloride and lithium chloride dissolved in tetrahydrofuran (THF) at a concentration of 0.6 M. This complex solution is known for its unique properties and reactivity, making it a versatile reagent in various chemical reactions and applications.

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  • LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF

    Cas No: 405204-22-0

  • USD $ 1.9-2.9 / Gram

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  • 405204-22-0 Structure
  • Basic information

    1. Product Name: LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF
    2. Synonyms: LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF;Lanthanum(III) chloride bis(lithium chloride) complex solution ;Lanthanum(III) chloride bis(lithium chloride) complex;dilithium,trichlorolanthanum,dichloride
    3. CAS NO:405204-22-0
    4. Molecular Formula: Cl5LaLi-
    5. Molecular Weight: 323.1
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 405204-22-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: 17℃
    4. Appearance: /
    5. Density: 1.05 g/mL at 25 °C
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF(CAS DataBase Reference)
    10. NIST Chemistry Reference: LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF(405204-22-0)
    11. EPA Substance Registry System: LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF(405204-22-0)
  • Safety Data

    1. Hazard Codes: F,Xn
    2. Statements: 11-19-36/37/38-40
    3. Safety Statements: 16-26-36/37
    4. RIDADR: UN 2056 3 / PGII
    5. WGK Germany: 2
    6. RTECS:
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 405204-22-0(Hazardous Substances Data)

405204-22-0 Usage

Uses

Used in Organic Synthesis:
Lanthanum(III) chloride bis(lithium chloride) complex solution 0.6 M in THF is used as a reagent for selective 1,2-additions. The complex solution facilitates the addition of nucleophiles to aldehydes and ketones, leading to the formation of alcohols. This selective addition is particularly useful in the synthesis of complex organic molecules, where control over the reaction is crucial.
Used in Grignard Additions:
In the field of organic chemistry, Lanthanum(III) chloride bis(lithium chloride) complex solution 0.6 M in THF is used as a mediator for Grignard additions. Grignard reagents are organomagnesium compounds that react with a wide range of electrophiles, such as carbonyl compounds, to form alcohols. The complex solution enhances the reactivity and selectivity of Grignard reagents, making it an essential component in various organic synthesis processes.
Used in Metal Exchange Reactions:
Lanthanum(III) chloride bis(lithium chloride) complex solution 0.6 M in THF is employed as a reagent for metal exchange reactions. These reactions involve the replacement of one metal with another in a compound, which can be useful for modifying the properties of a molecule or synthesizing new compounds with different metal centers.
Used in the Addition of Organometallic Compounds:
In the pharmaceutical and chemical industries, Lanthanum(III) chloride bis(lithium chloride) complex solution 0.6 M in THF is used as a promoter for the addition of organometallic compounds to sterically hindered, enolizable, or α,β-unsaturated ketones or imines. The complex solution enhances the reactivity of these substrates, allowing for the formation of new carbon-carbon bonds and the synthesis of complex organic molecules with potential applications in drug discovery and development.

Check Digit Verification of cas no

The CAS Registry Mumber 405204-22-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,0,5,2,0 and 4 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 405204-22:
(8*4)+(7*0)+(6*5)+(5*2)+(4*0)+(3*4)+(2*2)+(1*2)=90
90 % 10 = 0
So 405204-22-0 is a valid CAS Registry Number.

405204-22-0 Well-known Company Product Price

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  • Aldrich

  • (703559)  Lanthanum(III)chloridebis(lithiumchloride)complexsolution  0.6 M in THF

  • 405204-22-0

  • 703559-25ML

  • 621.27CNY

  • Detail
  • Aldrich

  • (703559)  Lanthanum(III)chloridebis(lithiumchloride)complexsolution  0.6 M in THF

  • 405204-22-0

  • 703559-100ML

  • 1,422.72CNY

  • Detail
  • Aldrich

  • (703559)  Lanthanum(III)chloridebis(lithiumchloride)complexsolution  0.6 M in THF

  • 405204-22-0

  • 703559-4X25ML

  • 1,862.64CNY

  • Detail

405204-22-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name dilithium,trichlorolanthanum,dichloride

1.2 Other means of identification

Product number -
Other names Lanthanum(III) chloride bis(lithium chloride) complex solution

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:405204-22-0 SDS

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