405284-69-7Relevant articles and documents
Hydrosilylation of (hetero)aromatic aldimines in the presence of a Pd(I) complex
Iovel,Golomba,Fleisher,Popelis,Grinberga,Lukevics
, p. 701 - 714 (2007/10/03)
The reaction of triethylsilane with heterocyclic and aromatic azomethines, catalyzed by the [Pd(allyl)Cl]2 complex, was studied. It was found that the reaction is affected by the nature of the functional groups in the aza and methine parts of the aldimine molecules, which were produced by the condensation of furan, thiophene, and benzene aldehydes with aniline and its derivatives. The reactivity of a series of imines is compared with their electronic and structural characteristics, determined by quantum-chemical methods. The corresponding furan, thiophene, and aromatic amines and also certain silylamines were synthesized.
