cas 405919-41-7, Phosphine, dicyclohexyl[2-(9-phenanthrenyl)phenyl]- | Articles data ｜lookchem

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405919-41-7

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A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: Novel ligand coordination
A catalyst system for the preparation of biaryls containing four ortho substituents via Suzuki coupling is described. The combination of a catalytic quantity of Pd2(dba)3 with either an electron-rich biarylphosphine or DPEPhos is effective using a wide range of substrates. The X-ray crystal structure of (dba)Pd(2-(9-phenanthryl)phenyl-dicyclohexylphosphine), in which the Pd is coordinated to the 9,10-double bond of the phenanthryl group, is also reported. Copyright
Yin, Jingjun,Rainka, Matthew P.,Zhang, Xiao-Xiang,Buchwald, Stephen L.
p. 1162 - 1163
(2002)
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Chemical Properties

Boiling Point: 611.6±34.0 °C(Predicted)
PSA: 13.59000
LogP: 9.43260

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