Synthesis of (-)-ilimaquinone via a radical decarboxylation and quinone addition reaction.
[reaction: see text] A stereoselective synthesis of (-)-ilimaquinone (4) is presented. The synthetic strategy is based on a novel radical decarboxylation and quinone addition methodology that produces quinone 7 from reaction of thiohydroxamic acid derivat
Ling, Taotao,Poupon, Erwan,Rueden, Erik J,Theodorakis, Emmanuel A
p. 819 - 822
(2007/10/03)
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