A simple and highly stereoselective route to (→).podocarpic acid
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Banerjee,Nasipuri,Pakrashi
p. 3952 - 3954
(2007/10/02)
Chemistry of the Podocarpaceae LXX. Synthesis and Cyclopentaannulation of a Diterpenoid Chromium Carbene Complex
A pentacarbonylcarbene chromium complex of the diterpenoid methyl O-methylpodocarpate has been prepared and its reactions with some alkynes have been studied with the aim of synthesising ring-C aromatic steroids.The use of diphenylacetylene resulted in cyclisation to give steroidal derivatives in moderate yield.
Cambie, Richard C.,Rutledge, Peter S.,Tercel, Moana,Woodgate, Paul D.
p. 171 - 186
(2007/10/02)
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