Unsaturated nitriles of the general formula CH2=CHnCN, where n>1, undergo metathesis at room temperature in the presence of the catalyst Re2O7-Al2O3, activated with a small amount of Me4Sn or Et4Sn.
Aardweg, Godefridus C. N. van den,Bosma, Ruud H. A.,Mol, Johannes C.
p. 262 - 263
(2007/10/02)
Homogeneous Metathesis of Unsaturated Nitriles
Unsaturated nitriles of general formula CH2=CHnCN, where 1 = n = 4, undergo metathesis in the presence of the catalyst system tungsten hexachloride-tetramethyltin with maximum reactivity for n = 2.
Bosma, Ruud H. A.,Kouwenhoven, Arjan P.,Mol, Johannes C.
p. 1081 - 1082
(2007/10/02)
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