41758-66-1 Usage
Uses
1. Used in Pharmaceutical Industry:
(±)-Stemonamine is used as a pharmaceutical compound for its potential therapeutic applications. The expression is: (±)-Stemonamine is used as a pharmaceutical compound for its potential therapeutic applications.
2. Used in Research and Development:
(±)-Stemonamine is used as a research compound for studying its chemical properties, structure, and potential interactions with other molecules. The expression is: (±)-Stemonamine is used as a research compound for studying its chemical properties, structure, and potential interactions with other molecules.
3. Used in Drug Discovery:
(±)-Stemonamine can be used as a starting point for drug discovery, as its unique structure and properties may lead to the development of new therapeutic agents. The expression is: (±)-Stemonamine is used as a starting point for drug discovery, with its unique structure and properties potentially leading to the development of new therapeutic agents.
4. Used in Natural Product Chemistry:
(±)-Stemonamine serves as an example of a naturally occurring alkaloid, contributing to the understanding of the chemical diversity found in nature. The expression is: (±)-Stemonamine is used as an example of a naturally occurring alkaloid, contributing to the understanding of the chemical diversity found in nature.
Check Digit Verification of cas no
The CAS Registry Mumber 41758-66-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 4,1,7,5 and 8 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 41758-66:
(7*4)+(6*1)+(5*7)+(4*5)+(3*8)+(2*6)+(1*6)=131
131 % 10 = 1
So 41758-66-1 is a valid CAS Registry Number.
41758-66-1Relevant articles and documents
Asymmetric Total Synthesis of (?)-Stemonamine and Its Stereochemical Stability
Fujita, Satoshi,Nishikawa, Keisuke,Iwata, Takayuki,Tomiyama, Taishi,Ikenaga, Hiroshi,Matsumoto, Kenji,Shindo, Mitsuru
, p. 1539 - 1543 (2018)
The first asymmetric total synthesis of (?)-stemonamine is described. The key reactions included intramolecular acylation to construct the seven-membered ring and a tandem [2+2] cycloaddition-Dieckmann condensation reaction using an ynolate to form the fully substituted cyclopentenone moiety. Racemization and epimerization of the natural product were first experimentally demonstrated.
First asymmetric total synthesis of (?)-isostemonamine and kinetic analysis of its isomerizations
Iwata, Takayuki,Tomiyama, Taishi,Fujita, Satoshi,Shindo, Mitsuru
, p. 712 - 718 (2019/04/26)
The first asymmetric total synthesis of (?)-isostemonamine is reported herein. The key reactions include the regioselective oxidation of the diketone, which is reported to be an intermediate in our synthesis of (?)-stemonamine. The chiral high-performance liquid chromatography (HPLC) analysis of the racemization and epimerization of (?)-isostemonamine revealed that isostemonamine isomerizes significantly faster than stemonamine.