EINE UNGEWOEHNLICHE Cl-F-AUSTAUSCHREAKTION BEI HALOGENALKYLTHIOETHERKETONEN
The syntheses of α-sulfinated compounds are described.Their reactions with HF are investigated.A Cl/F-exchange reaction with a spontaneous rearrangement into a β-fluorinated thioethercarbonylfluoride was observed.Factors influencing the reaction and the mechanism are discussed.
Bielefeldt, D.,Klauke, E.
p. 365 - 374
(2007/10/02)
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