Direct synthesis of: N -sulfenylimines through oxidative coupling of amines with disulfides/thiols over copper based metal-organic frameworks
A highly porous metal-organic framework based on supramolecular building blocks with pcu-topology (pcu-MOF) has been tested for the oxidative coupling of amines and disulfides or thiols to afford the N-sulfenylimines directly in good yields without the fo
Long, Wei,Qiu, Wenge,Li, Chuanqiang,Song, Liyun,Bai, Guangmei,Zhang, Guizhen,He, Hong
p. 40945 - 40952
(2016/05/19)
The reaction of oximes with tributylphosphine-phenyldisulfide: mechanistic insight and new synthetic possibilities
Reduction of oximes to imines with tributylphosphine-phenyldisulfide reagent proceeds via formation of phenylthioimino intermediates which are subsequently reduced to imines with tributylphosphine in the presence of a proton source. The latter reaction provides the first practical method for conversion of phenylthioimines into ketones.
Lukin, K. A.,Narayanan, B. A.
p. 214 - 220
(2007/10/03)
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