Enantioselective Synthesis of Isoflavanones by Catalytic Dynamic Kinetic Resolution
A ruthenium-catalyzed asymmetric transfer hydrogenation of racemic isoflavanones with dynamic kinetic resolution yields virtually enantiopure isoflavanols as single diastereomers. Subsequent oxidation gives rise to isoflavanones in high enantiomeric purit
Qin, Tao,Metz, Peter
p. 2981 - 2984
(2017/06/07)
Formation of hydridocobalt(iii) phthalocyanine by reaction of cobalt(ii) phthalocyanines with sodium borohydride and its reactions with antioxidant isoflavones
The reduction of substituted isoflavones with sodium borohydride catalyzed by cobalt(ii) phthalocyanines has been achieved efficiently to yield cis- and trans-isoflavan-4-ols under mild conditions via the formation of a hydridocobalt(iii) phthalocyanine i
Poonam,Kumari, Pratibha,Nagpal, Ritika,Chauhan, Shive M. S.
experimental part
p. 2639 - 2646
(2012/01/04)
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