433684-77-6

Basic information

• Product Name: Phenol, 2-(1-methylcyclopropyl)- (9CI)
• Synonyms: Phenol, 2-(1-methylcyclopropyl)- (9CI);2-(1-methylcyclopropyl)Phenol
• CAS NO: 433684-77-6
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.20168
• Product Categories: ALCOHOL
• Mol File: 433684-77-6.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Phenol, 2-(1-methylcyclopropyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(1-methylcyclopropyl)- (9CI)(433684-77-6)
• EPA Substance Registry System: Phenol, 2-(1-methylcyclopropyl)- (9CI)(433684-77-6)

Safety Data

• Hazardous Substances Data: 433684-77-6(Hazardous Substances Data)

Upstream product

• 95-56-7 2-hydroxybromobenzene 
• 71759-33-6 1-methyl-1-(o-aminophenyl)cyclopropane 
• 10178-53-7 1-bromo-2-((2-methylallyl)oxy)benzene 

Downstream Products

• 1206774-52-8 2-hydroxy-3-(1-methylcyclopropyl)-benzaldehyde 
• 1124145-87-4 C₁₀H₁₀Br₂O 

Relevant articles and documents

HETEROCYCLIC COMPOUND

Provided is a heterocyclic compound having a superior RBP4-lowering action and useful as a medicament for the prophylaxis or treatment of a disease or symptom mediated by an increase in RBP4 or retinol supplied by RBP4. A compound represented by the formula (I): wherein each symbol is as defined in the Description, or a salt thereof has a superior RBP4-lowering action, and is useful as a medicament for the prophylaxis or treatment of a disease or symptom mediated by an increase in RBP4 or retinol supplied by RBP4.

N-acylaminophenylcyclopropanes in reaction with nitrous acid generated in situ

The reaction of N-acylaminophenylcyclopropanes with HNO2 proceeds regioselectively with introduction of an N=O fragment into the three-membered ring and formation of the corresponding Δ2-isoxazolines. For ortho-substituted N-acylaminophenylcyclopropanes side processes were observed, caused by the intramolecular participation of the N-acyl group in conversions of the carbenium ions formed on opening the cyclopropane ring under the action of the nitrosating reagent, and by direct insertion of the modified ortho substituent into the three-membered ring.

On the Reactivity of o-Lithioaryl Ethers: Tandem Anion Translocation and Wittig Rearrangement

(matrix presented) Allyl and benzyl 2-lithioaryl ethers, generated by bromine-lithium exchange in THF, undergo a new tandem anion translocation-[1,2]-Wittig rearrangement allowing the isolation of the corresponding benzylic alcohols.