436088-93-6

Basic information

• Product Name: 2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE
• Synonyms: 2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE;TIMTEC-BB SBB010620
• CAS NO: 436088-93-6
• Molecular Formula: C12H19N
• Molecular Weight: 177.29
• Mol File: 436088-93-6.mol

Chemical Properties

• Boiling Point: 237.3 °C at 760 mmHg
• Flash Point: 91.1 °C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 0.0452mmHg at 25°C
• CAS DataBase Reference: 2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE(436088-93-6)
• EPA Substance Registry System: 2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE(436088-93-6)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 436088-93-6(Hazardous Substances Data)

Usage

Uses

Used in Chemical Research:
2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE is used as a research compound for exploring its chemical properties and potential applications in various fields. 2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE's unique structure and characteristics make it a subject of interest for scientists and researchers.
Used in Pharmaceutical Development:
2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE is used as a starting material or intermediate in the synthesis of pharmaceutical compounds. Its heterocyclic structure and functional groups may contribute to the development of new drugs with potential therapeutic applications.
Used in Material Science:
2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE is used as a component in the development of new materials with specific properties. Its chemical structure may be utilized to create materials with unique characteristics for various applications in industries such as electronics, plastics, and coatings.
Used in Environmental Applications:
2,6-DIALLYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE is used as a potential agent in environmental remediation processes. Its chemical properties may be harnessed to address environmental challenges, such as pollution control or waste management.

InChI:InChI=1/C12H19N/c1-4-6-11-8-10(3)9-12(13-11)7-5-2/h4-5,8,11-13H,1-2,6-7,9H2,3H3/p+1/t11-,12-/m1/s1

Upstream product

• 108-89-4 picoline 
• 688-61-9 Triallylborane 
• 157056-58-1 trans-2,6-diallyl-4-methyl-1,2,3,6-tetrahydropyridine 

Relevant articles and documents

New growth regulators of corn based on N-mono- and N,N-bis-3-butenyldichloroacetamides

Allylboration of imines, nitriles (including hydrocyanic acid), amides, lactams, aromatic azaheterocycles (pyridines, isoquinoline, and pyrrole) was used to synthesize a series of mono- and bis-3-butenylamines with different structures, which were converted to dichloroacetamides, new analogs of a known safener (herbicide antidote) Dichlormid successfully used in the cultivation of corn throughout the world. Biological tests for the germination of corn seeds showed that most of the dichloroacetamides obtained have growth-stimulating activity, which is mainly directed on the development of the root system. Compounds 2f, trans- and cis-2n, cis-2s, and 2t demonstrated outstanding activity, exceeding from two to three times the stimulating effect of Dichlormid on the developing root system of maize seedlings.

Synthesis of bridged azabicycles from pyridines and pyrrole by a diallylboration - Ring closing metathesis sequence

A straightforward method for the preparation of bridged azabicycles by a diallylboration-ring closing metathesis (RCM) sequence was elaborated. The precursors for the metathesis reaction were prepared by reductive irons-diallylation of aromatic heterocycles such as pyridines, isoquinoline and pyrrole with triallylborane and an alcohol. Heating of the irons isomers with one equivalent of triallylborane allowed the corresponding cis isomers - or (in the case of pyrrole) a mixture of cis and trans isomers - to be obtained. Boc protection of the amine function gave the precursor for the RCM reaction with axial orientations of allylic groups. The chemical yields of this stage are very good and the amounts of Grubbs' catalyst required for the reaction do not exceed 2.5 mol-% (first generation cat.) or 3.7 mol-% (second generation cat.). Azabicyclo[4.2.1]nonene, obtained from pyrrole, is a key structural motif of the toxin pinnamine. The structures of cis-1,3-diallyl-1,2,3,4- tetrahydroisoquinoline and azabicyclo[4.3.1]-decadiene were studied by single-crystal X-ray analysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.