BACTERIA IN ORGANIC SYNTHESIS : γ-ALKOXY-α-AMINOACIDS FROM RELATED α-AMINONITRILES.
The wild type strain Brevibacterium sp.R312 is able to hydrolyse water-soluble γ-alkoxyaminonitriles, under mild conditions, at pH value close to neutrality and at moderate temperature.The results reported here show that this technique is valuable for synthetic purposes.
Nucleophilic ring opening of aryl α-nitrocyclopropanecarboxylates with sterically protected but electronically effective carbonyl and nitro group. A new principle of α-amino acid synthesis (2-aminobutanoic acid a4-synthon)
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Seebach,Haner,Vettiger
p. 1507 - 1515
(2007/10/02)
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