Bifunctional initiators for free radical polymerization of non-crosslinked block copolymers
Novel bifunctional initiators have been designed with functional groups that independently produce free radicals. Initiators were synthesized to contain both diazene (-N=N-) and 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) moieties tethered by ester or ether linkages. It is anticipated that these compounds will be useful for producing a diverse number of block copolymers for applications in polymer-supported organic synthesis and materials science.
Gravert, Dennis J.,Janda, Kim D.
p. 1513 - 1516
(2007/10/03)
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