cas 47375-34-8, Boc-O-tert-butyl-L-tyrosine | Articles data ｜lookchem

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47375-34-8

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Highly selective fluorogenic multianalyte biosensors constructed via enzyme-catalyzed coupling and aggregation-induced emission
The development of a highly selective and fast responsive fluorogenic biosensor for diverse analytes ranging from bioactive small molecules to specific antigens is highly desirable but remains a considerable challenge. We herein propose a new approach by integrating substrate-selective enzymatic reactions with fluorogens exhibiting aggregation-induced emission feature. Tyrosine-functionalized tetraphenylethene, TPE-Tyr, molecularly dissolves in aqueous media with negligible fluorescence emission; upon addition of horseradish peroxidase (HRP) and H2O2, effective cross-linking occurs due to HRP-catalyzed oxidative coupling of tyrosine moieties in TPE-Tyr. This leads to fluorescence emission turn-on and fast detection of H2O2 with high sensitivity and selectivity. As a validation of the new strategy's generality, we further configure it into the biosensor design for glucose through cascade enzymatic reactions and for pathologically relevant antigens (e.g., human carcinoembryonic antigen) by combining with the ELISA kit.
Wang, Xiaorui,Hu, Jinming,Zhang, Guoying,Liu, Shiyong
supporting information
p. 9890 - 9893
(2014/08/05)

Peptide Synthesis. Part 3. Comparative Solid-phase Syntheses of Human β-Endorphin on Polyamide Supports using t-Butoxycarbonyl and Fluorenylmethoxycarbonyl Protecting Groups
Solid-phase syntheses of the 31 residue peptide human β-endorphin on polar polyamide supports are described.Minimisation of acidic reaction conditions by replacement of the customary t-butoxycarbonyl and benzyl-based protecting groups by fluorenylmethoxyc
Atherton, Eric,Caviezel, Mario,Fox, Hazel,Harkiss, Diana,Over, Hilary,Sheppard, Robert C.
p. 65 - 73
(2007/10/02)

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Chemical Properties

Melting Point: 113-118 °C
Boiling Point: 484 °C at 760 mmHg
Flash Point:246.5 °C
Density: 1.116 g/cm³
Storage Temp.:2-8°C
Vapor Pressure: 3.52E-10mmHg at 25°C
Refractive Index: 1.514
PKA: 3.00±0.10(Predicted)
BRN: 4327336
PSA: 84.86000
LogP: 3.77520

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