474023-22-8

Basic information

• Product Name: 2-Cyclohexen-1-one,4-methyl-3-(1-methylethyl)-,(4S)-(9CI)
• Synonyms: 2-Cyclohexen-1-one,4-methyl-3-(1-methylethyl)-,(4S)-(9CI)
• CAS NO: 474023-22-8
• Molecular Formula: C10H16O
• Molecular Weight: 0
• Product Categories: ISOPROPYL
• Mol File: 474023-22-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Cyclohexen-1-one,4-methyl-3-(1-methylethyl)-,(4S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one,4-methyl-3-(1-methylethyl)-,(4S)-(9CI)(474023-22-8)
• EPA Substance Registry System: 2-Cyclohexen-1-one,4-methyl-3-(1-methylethyl)-,(4S)-(9CI)(474023-22-8)

Safety Data

• Hazardous Substances Data: 474023-22-8(Hazardous Substances Data)

Upstream product

• 1404088-45-4 3-isopropyl-4-methylcyclohex-3-enone 
• 474022-92-9 (S)-3-benzenesulfonyl-4-methylcyclohex-2-enone 

Relevant articles and documents

Asymmetric approach toward chiral cyclohex-2-enones from anisoles via an enantioselective isomerization by a new chiral diamine catalyst

A 3-step asymmetric approach toward the optically active chiral cyclohex-2-enones from anisoles has been developed. The crucial asymmetric induction step is an unprecedented catalytic enantioselective isomerization of β,γ-unsaturated cyclohex-3-en-1-ones

Chemical synthons and intermediates

The invention provides novel six and seven-carbon termini-differentiated polypropionate stereotetrads and stereopentads useful in syntheses of natural products. The invention also provides a novel alkylative sulfenylation-desulfonylation process that efficiently transforms enantiopure epoxyvinyl sulfones to syn and anti dienylsulfides in two operations.

Syntheses of highly substituted enantiopure C6 and C7 enones

Enantiopure epoxyvinyl sulfones SS-9a, SS-9b, produced from Jacobsen epoxidation of 2-phenylsulfonyl 1,3-cyclohexa- and cycloheptadiene, are used as a template for the construction of substituted cycloalkenones and as chiral synthetic equivalents of enone