476468-30-1

Basic information

• Product Name: D-lyxo-Hexonic acid, 2,6-dideoxy-, delta-lactone (9CI)
• Synonyms: D-lyxo-Hexonic acid, 2,6-dideoxy-, delta-lactone (9CI)
• CAS NO: 476468-30-1
• Molecular Formula: C6H10O4
• Molecular Weight: 146.1412
• Product Categories: ALCOHOL
• Mol File: 476468-30-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: D-lyxo-Hexonic acid, 2,6-dideoxy-, delta-lactone (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: D-lyxo-Hexonic acid, 2,6-dideoxy-, delta-lactone (9CI)(476468-30-1)
• EPA Substance Registry System: D-lyxo-Hexonic acid, 2,6-dideoxy-, delta-lactone (9CI)(476468-30-1)

Safety Data

• Hazardous Substances Data: 476468-30-1(Hazardous Substances Data)

Upstream product

• 2053-00-1 D-digitoxose 
• 93338-33-1 (S)-3,6-dihydro-6-methyl-2H-pyran-2-one 
• 54826-92-5 (5R,6S)-5,6-dihydro-5-hydroxy-6-methylpyran-2-one 
• 952426-04-9 C₆H₈O₄ 
• 305378-69-2 3,4-O-isopropylidene-2,6-dideoxy-L-lyxo-hexopyrano-1,5-lactone 
• 952426-03-8 C₆H₈O₄ 
• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 
• 54621-88-4 4-O-acetyl-2,3,6-trideoxy-L-erythro-hex-2-enono-1,5-lactone 
• 473811-80-2 (2S,3S)-5-acetoxy-6-methyl-5,6-dihydropyran-2-one 
• 476468-23-2 (R)-but-3-enoic acid 1-methyl-allyl ester 
• 118992-11-3 (-)-6-(6R)-methyldihydropyr-4-en-2-one 
• 476468-21-0 (S)-but-3-enoic acid 1-methyl-allyl ester 
• 108645-77-8 (5S,6S)-5-hydroxy-6-methyl-5,6-dihydro-2H-pyran-2-one 
• 847659-79-4 But-3-enoic acid (E)-(S)-1-methyl-3-phenyl-allyl ester 

Relevant articles and documents

A first synthesis of sulfonic acid analogues of N-acetylneuraminic acid

Sulfonic acid analogues of N-acetylneuraminic are synthesized from 1-thio-l-fucoside derivatives with the introduction of an azido group at C-4 of the fucose moiety and carbanionic addition onto fully protected lactones. The analogues in the form of methy

A divergent strategy for constructing a sugar library containing 2,6-dideoxy sugars and uncommon sugars with 4-substitution

A practical strategy has been developed for delivering 2,6-dideoxy sugars and uncommon sugars with 4-substitution. This strategy employed Ferrier rearrangement reaction and BF3·OEt2-induced peroxidation to construct key intermediates 2,3-unsaturated glycosides and α,β-unsaturated lactones from peracetyl rhamnal. After further derivatization, four uncommon sugars with 4-substitution and eight uncommon sugar units with 3,4-disubstitution were successfully synthesized.

A divergent synthesis of uncommon sugars from furanaldehyde

A practical synthetic strategy has been developed for producing uncommon sugars. This method employed kinetic enzymatic resolution of 1-(2-furyl)ethanol, and followed by NBS-mediated Achmatowicz rearrangement to construct α,β-unsaturated lactones. After further derivatization, five representative uncommon sugar units were successfully synthesized. Georg Thieme Verlag Stuttgart.

A systematic strategy for preparation of uncommon sugars through enzymatic resolution and ring-closing metathesis

A systematic synthetic strategy has been developed for producing uncommon sugars. This method involved kinetic resolution allylic alcohol followed by ring-closing-metathesis (RCM) to generate optical pure lactones as the common precursors. After further d

Synthesis of 2,6-dideoxysugars via ring-closing olefinic metathesis.

[formula: see text] Grubbs' RuCl2 (=CHPh)(PCy3)2 (catalyst 1) and RuCl2(=CHPh)(PCy3)(IMess) (catalyst 2) complexes have been successfully utilized in the construction of beta,gamma-unsaturated delta-lactones containing various substitution patterns of methyl groups. Asymmetric dihydroxylation followed by reduction leads to 3,4-cis-dihydroxy-2,6-dideoxypyranoses, which have proven to play very important biological roles as key components of natural products.