478618-95-0

Basic information

• Product Name: 2-Cyclohexen-1-one,3-hydroxy-2-methoxy-5-methyl-(9CI)
• Synonyms: 2-Cyclohexen-1-one,3-hydroxy-2-methoxy-5-methyl-(9CI)
• CAS NO: 478618-95-0
• Molecular Formula: C₈H₁₂O₃
• Molecular Weight: 156.17908
• Product Categories: CYCLOHEXANONE
• Mol File: 478618-95-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Cyclohexen-1-one,3-hydroxy-2-methoxy-5-methyl-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one,3-hydroxy-2-methoxy-5-methyl-(9CI)(478618-95-0)
• EPA Substance Registry System: 2-Cyclohexen-1-one,3-hydroxy-2-methoxy-5-methyl-(9CI)(478618-95-0)

Safety Data

• Hazardous Substances Data: 478618-95-0(Hazardous Substances Data)

Upstream product

• 478618-94-9 2-Methoxy-5-methyl-3-(morpholin-4-yl)cyclohex-2-en-1-on 
• 326803-12-7 5-Methyl-3-(morpholin-4-yl)cyclohex-2-en-1-on 
• 478618-92-7 Ethyl-[4-methyl-2-(morpholin-4-yl)-6-oxocyclohex-1-en-1-yl]carbonat 
• 4341-24-6 5-methylcyclohexan-1,3-dione 
• 478618-93-8 2-Hydroxy-5-methyl-3-(morpholin-4-yl)cyclohex-2-en-1-on 

Relevant articles and documents

Chemistry of free cyclic vicinal tricarbonyl compounds ('1,2,3-triones'). Part 2. Redox reactions of 1,2,3-triones with ene-1,2-diols ('reductones'), 2-alkoxy-en-1-ols, ene-1,2-diamines, and related species

Midstanding carbonyl groups of cyclic 1,2,3-triones 4 possess outstanding electrophilic (electron-pair accepting) as well as oxidizing (one-electron accepting) properties. Their reactions with selected electron-rich C=C bonds as efficient nucleophiles AN reactions) and as efficient reducing agents (SET (single electron transfer) reactions) are studied. In a few cases, short-lived charge-transfer colors be observed. Particularly, free didehydro-5,6-O-isopropyliden-L-ascorbic acid (4g), its O,C-adduct 8g to 5,6-O-isopropylidene-L-ascorbic acid (1g), and via an independent pathway - the ostensible C,C-dimer 10a of mono-dehydrodimedone reductone were prepared. Intermediate radical anions 4 can be considered to be ideal representatives of dicapto-dative radicals. Novel large-scale syntheses of 3,4-dihydroxyfuran-2(5H)-one (1e) and of its vicinal trione 4e are presented.