Carbanion stabilization by distal silyloxy groups. Origin of the high diastereoselectivity in the formation of quaternary centers with aryllead(IV) triacetate reagents
(formula presented) Derivatives of methyl 5-hydroxy-2-oxo-1-cyclohexanecarboxylate react with aryllead(IV) reagents in high yield and with wide variation in diastereoselectivity. Ab initio calculations are consistent with a heretofore unrecognized attract
Konopelski, Joseph P.,Lin, Jinzhen,Wenzel, Philip J.,Deng, Hongbo,Elliott, Gregory I.,Gerstenberger, Brian S.
p. 4121 - 4123
(2007/10/03)
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