Ditopic azathioether macrocycles as hosts for transition metal salts
The synthesis and complexation of two heteroditopic lariat azathioether macrocycles L1 and L2 incorporating acylurea functionalised pendant arms are described; L1 and L2 are capable of simultaneously binding both the cationic and anionic moieties of a metal salt as confirmed by the structures of [PdCl2(L1)], [CuCl(L2)]2CuCl4 and [Ag(NO3)(L2)] and by 1H NMR studies in solution on [Ag(NO3)(L2)].
Design and synthesis of heteroditopic aza-thioether macrocycles for metal extraction
A series of pendant arm aza-thioether macrocycles containing hydrogen-bonding amide functionalities have been synthesised and the single crystal X-ray structures of [12]aneS3N-CONHCOPh, [12]aneS 3N-CSNHCOPh, [12]aneS2ON-CO
Glenny, Mark W.,Lacombe, Marie,Love, Jason B.,Blake, Alexander J.,Lindoy, Leonard F.,Luckay, Robert C.,Gloe, Karsten,Antonioli, Bianca,Wilson, Claire,Schroeder, Martin
p. 1755 - 1767
(2008/02/05)
Synthesis of 1,4-disubstituted piperazines. I.
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Verderame
p. 153 - 154
(2007/10/04)
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