485324-20-7

Basic information

• Product Name: N~1~,N~1~-diallyl-1,2-benzenediamine
• Synonyms: N~1~,N~1~-diallyl-1,2-benzenediamine
• CAS NO: 485324-20-7
• Molecular Formula: C12H16N2
• Molecular Weight: 188.26884
• Mol File: 485324-20-7.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N~1~,N~1~-diallyl-1,2-benzenediamine(CAS DataBase Reference)
• NIST Chemistry Reference: N~1~,N~1~-diallyl-1,2-benzenediamine(485324-20-7)
• EPA Substance Registry System: N~1~,N~1~-diallyl-1,2-benzenediamine(485324-20-7)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 485324-20-7(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 95-54-5 1,2-diamino-benzene 

Downstream Products

• 1262681-64-0 tert-butyl 2-(diallylamino)-phenylcarbamate 

Relevant articles and documents

Multistep reactions using microreactor chemistry

A microflow system for the investigation of multistep syntheses involving Pd-catalysed Heck reactions and Ru-catalysed ring-closing metathesis is described. A successful provision of reagent and catalyst delivery in a consecutive fashion allowed control over reaction parameters leading to fast optimisation. The performance of Heck reactions in multistep procedures was not as successful as in the single step coupling, whereas the ring-closing metathesis proved to be successful in the production of the desired compounds for further functionalisation. ARKAT-USA, Inc.

Radical-induced formation of some siloles and diazasiloles

The Bu3Sn radical-induced reaction of o-iodobenzylvinylsilanes and o-iodoallylsilanes leads to cyclic products in yields of 40-60%. These regioselective cyclizations occur with high preference for a 5-exo and a 7-endo mode with a 6-exo mode being absent. An example for ring closure via a 7-exo mode is described.