Comparative study of the reactivities of substituted 3-(benzoyl)benzyl carbanions in water and in DMSO
Benzyl-substituted carbanions produced by photodecarboxylation of ketoprofen derivatives have been examined in basic aqueous and DMSO solutions. Product studies, combined with kinetic measurements from laser flash photolysis, have allowed the determinatio
Llauger, Laura,Miranda, Miguel A.,Cosa, Gonzalo,Scaiano
p. 7066 - 7071
(2007/10/03)
First determination of absolute rate constants for the reaction of aroyl-substituted benzyl carbanions in water and DMSO
The prompt generation of carbanions II and III within the duration of the nanosecond laser pulse provides a way of evaluating absolute rate constants for their two decay pathways, protonation and cyclization, the latter resulting from an intramolecular nu
Llauger, Laura,Cosa, Gonzalo,Scaiano
p. 15308 - 15312
(2007/10/03)
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