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488150-72-7

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Enantioselective tandem formation and [2,3]-sigmatropic rearrangement of cyclic propargylic oxonium ylides catalyzed by dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate]
This paper describes the first examples of catalyst-dependent asymmetric induction in the periselective [2,3]-sigmatropic rearrangement of propargylic oxonium ylides generated by catalytic diazo decomposition. Catalysis of α-diazo-β-keto esters 4a-g using
Tsutsui, Hideyuki,Matsuura, Maya,Makino, Kazuishi,Nakamura, Seiichi,Nakajima, Makoto,Kitagaki, Shinji,Hashimoto, Shunichi
p. 283 - 295
(2007/10/03)

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