494798-73-1Relevant articles and documents
Born to be a Liquid Crystal: The role of fluorinated chain in the design and synthesis of new mesogens
Lopes, Luana D.,Merlo, Aloir A.
, (2021/12/13)
The title of this article is devoted to the collection of compounds synthesized in this work, in which all the molecules had an astonished performance as “characters of a scientific movie” about liquid crystals (LCs). Just like movie stars, all compounds
FLUORINE-CONTAINING NITRILE-OXIDE COMPOUND
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Paragraph 0233; 0234, (2016/01/30)
A stable and easily producible compound of the formula (I): wherein R1 represents a hydrocarbon group; and R2 and R3 represent each independently a hydrogen atom or a hydrocarbon group: provided that in at least one of Rs
Allylic and benzylic sp3 C-H oxidation in water
Ang, Wei Jie,Lam, Yulin
, p. 1048 - 1052 (2015/03/04)
A copper-catalyzed method for the oxidation of allylic and benzylic sp3 C-H by aqueous tert-butyl hydroperoxide (T-Hydro) in water using a recyclable fluorous ligand has been developed. The reaction procedure is tolerant to additional functional groups and the fluorous ligand could be reused with little loss of catalytic activity. This journal is
Synthesis and Liquid Crystal Properties of New Fluorinated Isoxazoles
Lopes,Merlo
, p. 149 - 157 (2015/07/15)
New fluorinated LC 3,5-diarylisoxazolines and 3,5-diarylisoxazoles have been synthesized and their thermal properties reported. Isoxazolines were synthesized using [3+2] 1,3-dipolar cycloaddition from nitrile oxide and alkenes with subsequent MnO2/s
NEW FLUOROUS TAGGING AND SCAVENGING REACTANTS AND METHODS OF SYNTHESIS AND USE THEREOF
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Page 50, (2008/06/13)
The present invention includes methods and compositions for increasing the fluorous nature of an organic compound by reacting it with at least one fluorous compound to produce a fluorous tagged organic compound. The increased fluorous nature of the fluorous tagged organic compound can then be utilized to separate the fluorous organic compound from untagged reagents, reactants, catalysts and/or products derived therefrom. The resultant fluorous tagged organic compound can be subjected to subsequent chemical transformations, wherein the fluorous nature of the tagged compound is utilized to increase the ease of separation of the fluorous tagged organic compound from untagged reagents, reactants, catalysts and/or products derived therefrom, after each chemical transformation. The chemical transformations result in a second fluorous tagged organic compound wherein the fluorous nature of the second fluorous tagged organic compound can then be reduced by removing the fluorous group therefrom, thereby producing a second organic compound that may be employed as a pharmaceutical compound or intermediate, or a combinatorial library component.