- Synthesis, spectra and redox properties of Ru(II)carbonyl Schiff base complexes
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The reaction of bidentate Schiff bases (LL′) viz. H-salampy, H-salmet or H-salchx with [RuHCl(CO)(B)(PPh3)2] (where B = triphenylphosphine, pyridine, piperidine and morpholine) yield Ru(II) complexes of the type [RuCl(CO)(B)(PPh3)(LL′)]. All the complexes have been characterized by elemental analysis, spectral (1R, electronic and 1H NMR) and electrochemical data. An octahedral structure has been tentatively proposed for all these complexes.
- Ramesh,Venkatachalam
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p. 2285 - 2287
(2007/10/03)
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