- NUCLEOPHILICITY OF AZIDE ION IN THE MICELLAR PSEUDOPHASE
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The reaction of azide ion with 2-chloro-3,5-dinitropyridine, n-butyl-4-nitrobenzenesulfonate and n-butyl-4-bromobenzenesulfonate is catalyzed by cationic micelles of cetyltrimethylammonium salt (CTAX, X = Cl-, Br-, 0.5 SO2-, OMes, N3-).The second-order rate constants in the micellar pseudophase is smaller than that in water.
- Al-Lohedan, Hamad A.
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