Catalytic decarbonylation of epoxyaldehydes: Applications to the preparation of terminal epoxides
A catalytic decarbonylation reaction for epoxyaldehydes is reported. This reaction may be sequentially used with known asymmetric methods to access optically active mono- and disubstituted terminal epoxides, as illustrated for a key example. Georg Thieme Verlag Stuttgart.
Morandi, Bill,Carreira, Erick M.
experimental part
p. 2076 - 2078
(2011/04/15)
Revisiting the Corey-Chaykovsky reaction: The solvent effect and the formation of β-hydroxy methylthioethers
The classical Corey-Chaykovsky (CC) reaction of ketones in ethereal solvents (i.e., THF or Et2O) resulted in the production of a significant amount of β-hydroxy methylthioether 2 along with normal epoxide product 1. Some interesting and synthet
Peng, Yu,Yang, Jin-Hui,Li, Wei-Dong Z.
p. 1209 - 1215
(2007/10/03)
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